Surrounding planet Earth are different atmospheres. Exosphere is a transitional zone that separates Earth from space. Thermosphere and Mesosphere are the adjacent atmospheres as you move towards Earth. Closest to the planet are the Stratosphere and Troposphere, the troposphere being the lowest layer of the atmosphere, the site of our weather, our rain and our wind. Observable phenomena, and knowledge of chemical reactions, have built a large database with regard to ozone depletion. Much is known — the consequences of CFC’s, how ozone is built, how it is destroyed — but theoretical explanations still predominate.
What we do know is the Universe, including the Sun, releases stored energy in a range of alternating electric and magnetic fields. Scientists have named the shortest detectable wavelengths Gamma rays and X-rays. Ultraviolet waves are next on the spectrum:
UVC in the 10 to 290 nanometer band,
UVB, 290 to 320 nanometers,
UVA, 320 to 400 nanometers.
Gasses and particulates destroy ozone
Volcanic emissions are a natural way to destroy ozone. If a volcanic eruption is strong enough it will send particulates and gases into the upper troposphere and stratosphere. Scientists estimate that the Mount Pinatubo eruption in June 1991 had eruption columns at an altitude of 35 kilometers, higher than the average concentration layer of ozone. Adding to this natural effect, two months later the volcanic Mount Hudson in southeast Chile erupted.Volcanic eruptions are a natural phenomenon, a temporary loss of ozone that the Earth life syste
m incorporates into its biosystem.
Carbonyl sulphide is a photochemical reaction of sulphur. It contains organic compounds and was a major factor in causing the stratospheric ozone depletion of 1991/1992. The ozone hole over Antarctica was the largest recorded following the two eruptions.
Recording of ozone has been taking place over the Antarctic for the past fifty years.
Volcanic emission particulates and chemicals are not the only factors involved in ozone depletion.
Chlorine and Bromine are known to be two major causes of recent ozone breakdown.
For instance, when a chlorine radical connects with ozone, it produces oxygen and chlorine oxide, ClO.
This begins a chain reaction where the chlorine oxide quickly releases the chlorine radical — which then attaches itself to another ozone molecule, producing a new oxygen molecule and chlorine oxide molecule, which quickly releases, and so on.
CFCs, halon, hydrochlorofluorocarbons, methyl bromide, methyl chloroform and carbon tetrachloride, all are recognized as manufactured compounds that when released into the atmosphere significantly destroy ozone.
With an increase in biomass burning, industrial, and waste management activities, and the use of fertilizer — tests have shown soil-borne microorganisms produce nitrogen oxides as a decay product — more nitrogen oxides are being released into the atmosphere.
While much of the nitric oxide and nitrogen dioxide returns to the ground, nitrous oxide, commonly known as laughing gas, remains. N2O acts as a greenhouse gas. It also rises into the stratosphere where it is decomposed by UV radiation. Some N2O is converted to NO. Nitrogen oxide reacts catalytically with ozone to produce nitrogen dioxide and oxygen.
Aircraft as they fly around the world emit nitrogen oxides in their exhaust. A chemical process takes place in the wake of the exhaust transforming fumes into particulates. With an increasing number of planes flying near the tropopause, both nitrous oxide, and particulates, become readily available for transfer to the stratosphere. Aircraft exhaust is a factor in Ozone depletion.